Characterization of dissolved organic matter in surface water and groundwater: a dataset for the Seine River basin (France)
Carbon fluxes in river networks represent a major component of the carbon cycle, but they are difficult to estimate at large scale. In particular, the physicochemical properties of organic matter (OM) and its contribution to river carbon fluxes remain poorly understood. In this context, this paper presents a dataset for quantifying and characterizing dissolved organic carbon (DOC) in a regional river basin, the Seine River basin in France (76 000 km2), which is subject to numerous human pressures. The dataset is the result of several sampling campaigns conducted over a 14-year period (2011–2024). A total of 1047 samples were collected from various water types (surface water, groundwater and treated effluents from wastewater treatment plants, WWTPs) at sites across the basin encompassing diverse land uses. Dissolved organic matter (DOM) was characterized both quantitatively, by measuring the concentration of dissolved organic carbon (DOC), and qualitatively, through analysis of its optical properties using UV-Visible absorbance and excitation–emission matrix (EEM) fluorescence spectroscopy. Additionally, using the 45-day incubation method, the biodegradable fraction of DOC, which plays a particularly significant role in river water quality, was estimated for 27 % of the samples. The content and properties of OM in the Seine River basin vary significantly depending on the site, measurement period, and type of water sampled. DOC concentrations are generally higher in WWTP discharges and gravel pits. The biodegradable fraction of DOC is higher in samples from WWTP discharges and from groundwater in a forested alluvial plain. OM in the basin generally displays a low level of aromaticity but is hydrophilic and characterized by strong biological activity. This biological activity is particularly pronounced in the treated effluents from small-capacity WWTPs, where OM is mainly of microbial origin, and in gravel pits, where OM consists primarily of protein-type compounds. Groundwater typically contains a mixture of OM of both terrestrial and microbial/biological origins. These data may be useful for future studies of (i) the organic carbon cycle at the regional basin scale, (ii) the characteristics of OM across different compartments of a hydrosystem, and (iii) river metabolism. The dataset is available at https://data.indores.fr/privateurl.xhtml?token=a6b58980-3280-4a1b-9311-a0b401955e75.
(04/03/2026)
METIS, EPHE, PSL, INSU - CNRS, SU, CNRS, EPOC, EPHE, PSL, UB, INSU - CNRS, CNRS, LEESU, UPEC UP12, ENPC, IP Paris, SIAAP, GEOSCIENCES, PSL
Holocene climatic changes in the Kerguelen archipelago (South Indian Ocean) based on marine and lacustrine palaeoclimatic archives
Climatic variability in the Southern Hemisphere is largely controlled by the latitudinal position of the Southern Hemisphere Westerly Winds (SHW), whose migration influences precipitation, temperature, and Antarctic upwelling. This study presents the results of analyses of two lacustrine sediment cores from Lake Armor, located on the subantarctic Kerguelen Islands (49 • 15′S, 69 • 10′E), within the SHW belt. Lipid biomarkers (Glycerol Dialkyl Glycerol Tetraethers, n-alkanes, and their hydrogen isotopes) were used to reconstruct mean annual air temperature above freezing (MAF) and humidity conditions. These records are compared with a high-resolution diatom-based summer sea surface temperature (SST) reconstruction from marine core MD11-3353, situated 150 km southwest of Lake Armor. In the late glacial and Early Holocene, our results reveal a period of warm air temperature, comparable to current values and very warm sea surface temperature, 5°C above the current values. Around 9000 cal a BP, an abrupt transition occurred, marked by a cooling of 5°C in SST and 1.5°C in MAF, interpreted as a northward migration of the SHW and associated oceanic fronts. The Mid-to-Late Holocene period is characterized by pronounced MAF variability, including a notably warm interval between 3000 and 2000 cal a BP, when n-alkane dD suggests the prevalence of wetter conditions. Since ~250 cal a BP, a southward migration of the SHW has produced a 2.5°C rise in MAF. Our findings are overall consistent with previous studies from the Indian Ocean, but permit us to go a step further as by comparing SSTs and air temperatures. This suggests that SST is not a reliable predictor of air temperature on the Kerguelen Islands, particularly during the Early Holocene. We hence argue that Kerguelen air temperature is predominantly controlled by the position of westerly winds, as an indicator of reorganisations in air mass trajectories.
(Quaternary Science Reviews. vol. 375, n° 0277-3791, pp. 109753, 01/03/2026)
EDYTEM, USMB [Université de Savoie] [Université de Chambéry], CNRS, Fédération OSUG, LGL-TPE, ENS de Lyon, UCBL, INSU - CNRS, UJM, UJM EPE, CNRS, EPOC, EPHE, PSL, UB, INSU - CNRS, CNRS, MIO, IRD, AMU, INSU - CNRS, UTLN, CNRS, LOCEAN-VOG, LOCEAN, MNHN, IRD, INSU - CNRS, SU, CNRS, IPSL (FR_636), ENS-PSL, UVSQ, CEA, INSU - CNRS, X, CNES, SU, CNRS, UPCité, LOCEAN-VALCO, LOCEAN, MNHN, IRD, INSU - CNRS, SU, CNRS, IPSL (FR_636), ENS-PSL, UVSQ, CEA, INSU - CNRS, X, CNES, SU, CNRS, UPCité, UiB, IP, INSU - CNRS, CNRS, JAMSTEC, INEE-CNRS, CNRS, INSU - CNRS
Origin and evolution of giant comet marks along the North Atlantic Deep-Water flow on the Demerara plateau
The Demerara Plateau, located in the equatorial Atlantic, is particularly well-suited for recording the activity of the Deep Western Boundary Current (DWBC), which transports North Atlantic Deep Water (NADW) southward into the Atlantic basin. This current, active between 1500 and 3500 m depth, constitutes the deep part of the global thermohaline circulation and plays a crucial role in climate regulation. The Demerara Plateau is remarkable for the abundance and wide distribution of comet mark-type sedimentary structures, which can reach several kilometres in length. These hydrodynamic bedforms, interpreted as erosional features associated with strong bottom currents, are currently used as proxies for deep currents velocities, with minimum formation thresholds estimated between 0.60 and 0.75 m/s according to the literature (Rebesco et al., 2014; Werner et al., 1980). The DIADEM (Dive At DEMerara) oceanographic cruise (Basile and Loncke, 2023) enabled detailed investigation of one such structure using a combination of complementary tools with the aim of better understanding their functioning and evolution with in-situ observation, physical records, and sampling. Those new data were also combined with formerly acquired high-resolution seismic data, allowing a new vision of these bedforms their formation, and their evolution over time. The main findings are the following: (1) comet-marks localize on carbonate mass transported blocs outcropping on the seafloor; (2) Clearly show a polyphase evolution of the bedforms of comet mark presenting alternations of erosion and sedimentation phases. The bedforms therefore record long-term variations in bottom current activity with an alternation of intense hydrodynamic events (erosion) and quieter hydrodynamic periods (deposition) through time, reflecting a complex hydrodynamic history; (3) At present, comet-marks recorded a significant decrease in current velocity within the erosional zones located inside the comet tails associated with fined-grained sediments infill in this area, highlighting the need for cautious interpretation of such features as direct indicators of present-day current intensity; (4) Finally, a result that was not necessarily anticipated but documented by exploring those bedforms with the Nautile submersible, comet-marks host quite important benthic and epibenthic biodiversity with a wide variety of associated species.
(Marine Geology. vol. 493, n° 0025-3227, pp. 107717, 01/03/2026)
CEFREM, UPVD, INSU - CNRS, CNRS, EPOC, EPHE, PSL, UB, INSU - CNRS, CNRS, LOCEAN-CYBIOM, LOCEAN, MNHN, IRD, INSU - CNRS, SU, CNRS, IPSL (FR_636), ENS-PSL, UVSQ, CEA, INSU - CNRS, X, CNES, SU, CNRS, UPCité, LOCEAN-VALCO, LOCEAN, MNHN, IRD, INSU - CNRS, SU, CNRS, IPSL (FR_636), ENS-PSL, UVSQ, CEA, INSU - CNRS, X, CNES, SU, CNRS, UPCité, LOPS, IRD, IFREMER, INSU - CNRS, UBO EPE, CNRS, GEO-OCEAN, UBS, IFREMER, INSU - CNRS, UBO EPE, CNRS, ENTROPIE [Réunion], IRD, UR, CNRS, ISTerre, IRD, INSU - CNRS, USMB [Université de Savoie] [Université de Chambéry], CNRS, Fédération OSUG, UGA
Polar Front System Variability and Its Control on Export Rain Ratio Over the Past 800 ka: Implication for Atmospheric p CO 2 Changes
Little is known about long-term variability in the organic carbon to carbonate carbon export rain ratio, despite its key role in the global carbon cycle. Here, we reconstruct glacial-interglacial changes in the sedimentary rain ratio over the Southern Ocean, using micropaleontological (coccoliths and foraminifera) and geochemical (CaCO 3 , Total Organic Carbon (TOC), δ 13 C, C/N) records from sediment core MD04-2718, located in the Polar Front Zone (PFZ, Indian sector), complemented with published data sets from across the Subantarctic Zone (SAZ). We show that sedimentary CaCO 3 primarily reflects the export of biogenic calcium carbonate by calcifying phytoplankton and zooplankton, while TOC captures the export of phytoplanktonderived organic carbon. The sedimentary TOC/CaCO 3 ratio thus serves as a robust proxy for past variations in the balance between organic and inorganic carbon export and hence, of the export rain ratio. Our results indicate higher rain ratios during glacial periods, driven by enhanced organic carbon export, as colder conditions and intensified iron-rich dust inputs stimulated diatom productivity. In contrast, lower rain ratios during interglacials reflect strengthened biogenic carbonate export, as warmer conditions and elevated macronutrient supply from reinvigorated Southern Ocean upwelling supported coccolithophore and foraminifera blooms. These shifts reflect an ecological seesaw between silicifying and calcifying phytoplankton modulated by changes in westerly wind intensity and the position of the Polar Front. The negative correlation between rain ratios from the SAZ-PFZ and atmospheric pCO 2 suggests that enhanced organic carbon export during glacials likely promoted deepocean carbon sequestration, modulating atmospheric CO 2 levels.
Plain Language Summary Marine phytoplankton uses sunlight to convert atmospheric carbon dioxide (CO 2 ) into organic matter, which helps to store carbon in the ocean. However, certain plankton species produce calcium carbonate shells, a process that reduces this carbon storage by increasing CO 2 levels in surface waters. The balance between organic carbon and carbonate export-known as the "rain ratio"-is an important indicator of how marine life influences atmospheric CO 2 . In this study, we reconstructed changes in the rain ratio over the past 800,000 yrs from sediment samples collected in the Southern Ocean. We found that during cold glacial periods, a higher rain ratio corresponds to increased productivity of plankton with silica-based shells. During warmer interglacial periods, a lower rain ratio reflects dominance by plankton with calcium carbonate shells. These shifts between plankton communities are driven by changes in ocean conditions-cold, iron-rich waters favor silica-forming plankton, while warmer, nutrient-rich waters promote calcifiers. These environmental changes are linked to the strength of westerly winds and movements of ocean fronts. Our findings suggest that biological productivity in the Southern Ocean has played an important role in regulating Earth's carbon cycle and atmospheric CO 2 levels over long climate cycles.
(Paleoceanography and Paleoclimatology. vol. 41, n° 2572-4525, 01/03/2026)
GEOPS, INSU - CNRS, CNRS, LSCE, UVSQ, INSU - CNRS, CNRS, DRF (CEA), CEA, NIOZ, PALEOCEAN, LSCE, UVSQ, INSU - CNRS, CNRS, DRF (CEA), CEA, EPOC, EPHE, PSL, UB, INSU - CNRS, CNRS, EPHE, PSL, UB, CR2P, MNHN, SU, CNRS, ESE, CNRS, UNIBE, UNIL
Reconstruction of last millennium sea surface temperature on 1° grid using a random forest algorithm
Climate models and theoretical evidence show that the ocean drives climate from sub-decadal to centennial timescales through a variety of processes and their interactions. The range of direct climate observations, arelhowever, is too short to understand the exact role of the ocean in shaping observed and future climate variability on top of anthropogenic climate change. In the present study, we use a large set of paleoclimate records combined with a random forest algorithm to reconstruct a gridded dataset of sea surface temperatures since 850 C.E. to provide a better framework for the study of ocean surface variability. In line with modeling and paleodata studies, our reconstruction suggests that natural climate forcings have importantly influenced the last millennium climate variability. Our reconstruction also suggests that North Atlantic SST multidecadal variability influences Pacific SST on decadal timescales. However, the latter result is shown to be strongly dependent on background climate conditions. This new reconstruction offers a useful resource for testing the capabilities of climate models to reproduce the linkages between Atlantic and Pacific as well as the response to external forcings.
(Global and Planetary Change. vol. 258, n° 0921-8181, pp. 105279, 01/03/2026)
AOPP, EPOC, EPHE, PSL, UB, INSU - CNRS, CNRS, LOCEAN, IPSL, ENS-PSL, PSL, UVSQ, UPMC, CEA, INSU - CNRS, X, IP Paris, CNES, CNRS, MNHN, IRD, UPMC, INSU - CNRS, CNRS
Multi-annual evolution of coastal dunes: Transition from fixed to transgressive dunes state
Most of coastal dunes located in temperate latitudes, especially in the Northern Hemisphere, are relatively stable. However, along the Gironde coast (SW France) substantial dune remobilization has been observed over the last decade following major marine erosion events during the 2013-2014 winter. This study is based on the analysis of a robust dataset including (i) 10 high-resolution Digital Terrain Models (DTMs) derived from airborne LiDAR surveys conducted over a 12-year period (2011-2023) and (ii) 7 Satellite-derived Digital maps of dune vegetation cover derived from Sentinel-2 satellite images acquired between 2017 and 2023. These morphological and biological parameters are linked to forcing parameters derived from observed wind data, to provide a comprehensive analysis of coastal dune changes related to the transition from vegetation-fixed dunes to the development of transgressive dunes. For the first time, morphological and vegetation dynamics are explored over a large spatial scale (tens of km), covering a range of initial dune morphology and sediment supply.
Dunes have transitioned from stable to transgressive states primarily driven by sediment stoss slope recycling process (cannibalism) across a gradient of alongshore variable dune sediment budget, ranging from slightly negative to notably positive (+10 to 15 m 3 /m/yr), Along this coast, transgressive dunes defined as dune migrating via similar stoss and lee slope migration rates, have tripled in number over the last 10 years (reaching ≈ 15 km or 17.3 % of the studied coast). At the center of the Gironde coast where dunes are heavily remobilised, the lee slope of the dune translates landward at a rate of several meters to more than 10 m/year. In the following years, dunes will probably continue to migrate and remobilise across a broader scale if no re-stabilization management plan is implemented.
(CATENA. vol. 264, n° 0341-8162, pp. 109787, 01/03/2026)
BRGM, EPOC, EPHE, PSL, UB, INSU - CNRS, CNRS, CEFREM, UPVD, INSU - CNRS, CNRS, ONF
Drastic changes in tidal hydrodynamics following seagrass decline and their seasonal variations in a shallow lagoon
Over the past decades, seagrasses have drastically declined worldwide, reducing their capacity to regulate flow conditions. Intertidal species have been particularly affected by this decline, yet there is limited understanding of how intertidal seagrass loss influences hydrodynamics in shallow coastal lagoons. In this study, we use a 3D flow-vegetation model that accounts for vegetation effect on mean and turbulent flow, as well as flow-induced leaf bending, to investigate how tidal hydrodynamics respond to seasonal and multi-decadal changes in intertidal seagrass characteristics. The model is applied to the Arcachon lagoon (France), colonized by extensive Zostera noltei and Zostera marina meadows. This study reveals that a short-leaf and flexible seagrass species such as Zostera noltei can regulate tidal hydrodynamics throughout the lagoon due to the presence of broad and dense meadows on the tidal flats. In summer, seagrass decline leads to a significant increase in the 75th percentile in bottom flow velocities (+100 %) on the tidal flats, but to a decrease in the channels (−20 %). However, in winter, the response of tidal hydrodynamics to the reduction in seagrass coverage is far less pronounced. Comparison of simulated scenarios reveals that the multi-decadal decline of Zostera meadows with summer characteristics and the seasonal loss between summer and winter lead to modifications in tidal-flow parameters (current velocities, tidal asymmetry, high-tide water level) of a comparable magnitude. These changes in hydrodynamics likely enhance suspended sediment concentration, reducing light availability, contributing to further seagrass loss, and modifying sediment management for stakeholders due to enhanced siltation in channels.
(Coastal Engineering. vol. 205, n° 0378-3839, pp. 104948 (34p.), 01/03/2026)
LERAR, COAST, IFREMER, EPOC, EPHE, PSL, UB, INSU - CNRS, CNRS
Seasonal dynamics of cable bacteria in an estuarine intertidal mudflat subject to green tides: Implications for the foraminiferal community and test preservation
As many coastal areas draining intensive agricultural activities, Ledano estuary mudflats (French Brittany) experience Ulva proliferation, causing green tides. We studied the seasonal dynamics of sulphoxidizing cable bacteria from April 2019 to July 2020 using microsensors (O 2 , pH, H 2 S). The activity of these filamentous bacteria, called electrogenic sulphur oxidation (eSOx), results in strong acidification and in pore-water CO 3 2depletion in the first few centimeters of sediment (within the suboxic zone). Living and dead benthic foraminiferal assemblages were studied in July 2020 to observe the effects of eSOx on the calcareous meiofauna and their shell preservation in the sediment. eSOx was patchy on the mudflat but persistent throughout the year. It contributed up to 45% of oxygen consumption during the algal mat decay, and exceeded 100% during the flooding period suggesting stimulation by nitrate inputs. The corrosive effect was maximal in July 2020 (ΔpH ~ 1.7, [CO$_3^{2-}$]calc < 10 μM). The living foraminiferal community was sparse and nearly monospecific, dominated by the calcareous species Haynesina germanica, probably due to green tides coupled with eSOx-driven acidification. However, living specimens of H. germanica showed no signs of advanced dissolution of their shell suggesting a biological capacity to survive in such environmental acidification, potentially linked to their photosynthetic capability. In contrast, the dead assemblages displayed greater diversity despite a loss of about 20% of the calcareous shell recording with depth due to the synergetic effect of low salinity and eSOx. Overall, this study shows that green tides strongly influence cable bacteria activity and then, sedimentary biogeochemical processes in eutrophic coastal environments.
(Journal of Sea Research (JSR). vol. 210, n° 1385-1101, pp. 102683, 01/03/2026)
LPG, UM, UA, INSU - CNRS, CNRS, Nantes univ - UFR ST, Nantes Univ, EPOC, EPHE, PSL, UB, INSU - CNRS, CNRS
Metal pollution and floral abundance influence the diversity of flower visiting insects
Soil pollution with metals is a worldwide problem with negative effects on ecosystem health. Metals are persistent and can accumulate in the food web, with potential toxic effects for most organisms. Some metal-tolerant plants can accumulate metals in their aboveground parts, including the pollen and nectar of their flowers. Therefore, insects visiting these flowers are exposed to these toxic elements. They can also be influenced by the plant species turnover observed along pollution gradients. Surprisingly, the impact of soil metal contamination on pollinating insect diversity has rarely been studied. To fill in this gap, we carried out a study in a former mining valley in the French Pyrenees with metal contamination by Zn, Pb and Cd. We estimated the richness and community composition of insects visiting the flowers of metal-tolerant and metal-intolerant plant species in 96 plots along metal pollution gradients. Insect richness did not change along the pollution gradient and was similar between metal-tolerant and metal-intolerant plant species. On the contrary, insect community composition changed along the gradient and differed between plant types. We also found that insect species richness increased with the flower abundance of the focal plant. This study showed that flowers of metal-tolerant plants, including hyper-accumulator species, are visited by several insect species and harbour a distinct pollinator community. The ingestion of metal-rich nectar or pollen may have lethal or sub-lethal effects for these flower-visiting insects. Further experimental studies are needed to determine if metal-rich floral resources act as an ecological trap for some of these species.
(Arthropod-Plant Interactions. vol. 20, n° 1872-8855, pp. 16, 26/02/2026)
BioGeCo, UB, INRAE, EPOC, EPHE, PSL, UB, INSU - CNRS, CNRS
On the relations between morphotectonics, seismicity, perennial and sporadic hydrothermalism on the volcanic island complex of Milos (Greece)
The volcanic island complex of Milos, situated ∼200 km north of the Hellenic subduction zone, records the interplay of volcanic, tectonic, and gravitational processes within multidirectional, polyphased rift systems that developed throughout the Mio-Plio-Quaternary. Its active and seismogenic fault network hosts both perennial and transient hydrothermal venting zones, offering a natural laboratory to examine fluid circulation within a volcanic arc built on stretched continental crust. This study refines the relationships between magmatism, seismicity, and hydrothermal activity, with implications for local geological hazards. Two new morpho-tectonic sketches are presented. The first places the Milos volcanic center within the structural framework of the Aegean microplate; the second illustrates the spatial organization of the Milos tectono-hydrothermal-volcanic system. These reconstructions integrate detailed physiographic analyses (relief, slope), field observations, and multidisciplinary datasets on seismicity, hydrothermalism, and mineralization. At the scale of the Aegean microplate, (i) NE-SW faults are attributed to extensional deformation along the Mid-Cycladic Lineament; (ii) E-W faults relate to the opening of the Milos, Cretan, and Christiana basins, parallel to the mid-Miocene West Cycladic Detachments; (iii) NW-SE faults correspond to the Myrtoon Basin and Gulf of Milos openings, the latter being closed to the south by the Fyriplaka volcano; and (iv) N-S faults controlling the Zephyria graben and the eastern margin of Milos are continuous with Cretan fault systems and are parallel both to the Eocene trans-Cycladic thrust in the region and to magnetic anomalies in the subducted Tethyan oceanic crust south of the Hellenic subduction zone. At the archipelago scale, seismicity, hydrothermal venting, alteration zones, and phreatic explosions are concentrated in the hanging wall of the Achivadolimni fault, along or near the intersections of the N-S Zephyria and NW-SE Fyriplaka grabens, directly above the inferred magma chamber. Microearthquake hypocentres, likely linked to fluid-induced fault dilation, occur beneath the Gulf of Milos (∼7 km) and Fyriplaka volcano (∼5 km). Their distribution suggests a genetic link between the intersecting grabens, cooling of isotherms beneath the gulf by descending seawater, surface hydrothermal manifestations, and tectonic earthquakes (e.g., Mw 5.3 Milos, 1992). A shallow hydrothermal convection loop (<3 km) probably overlies a magmatic reservoir where fluids accumulate beneath a self-sealed, low-permeability cap, possibly corresponding to a thermal brittle-ductile transition (370-450 °C). Co-seismic ruptures may locally breach this barrier, inducing "arterial fault" behaviour along the Achivadolimni fault. Pulsating hydrothermal activity and historical phreatic eruptions are interpreted as surface expressions of transient injections of over-pressurized magmatic fluids, leading to decompression, phase transitions, and fluid
(Bulletin de la Société Géologique de France. vol. 197, n° 0037-9409, 22/02/2026)
EPOC, EPHE, PSL, UB, INSU - CNRS, CNRS, LGL-TPE, ENS de Lyon, UCBL, INSU - CNRS, UJM, UJM EPE, CNRS, LGENS, INSU - CNRS, CNRS, ENS-PSL, PSL, I2M-BX, UB, CNRS, INRAE, NKUA