Removal of xenobiotics from effluent discharge by adsorption on zeolite and expanded clay: an alternative to activated carbon?
Xenobiotics such as pesticides and pharmaceuticals are an increasingly large problem in aquatic environments. A fixed-bed adsorption filter, used as tertiary stage of sewage treatment, could be a solution to decrease xenobiotics concentrations in wastewater treatment plants (WWTPs) effluent. The adsorption efficiency of two mineral adsorbent materials (expanded clay (EC) and zeolite (ZE)), both seen as a possible alternative to activated carbon (AC), was evaluated in batch tests. Experiments involving secondary treated domestic wastewater spiked with a cocktail of ten xenobiotics (eight pharmaceuticals and two pesticides) known to be poorly eliminated in conventional biological process were carried out. Removal efficiencies and partitions coefficientswere calculated for two levels of initial xenobiotic concentration, i.e, concentrations lower to 10 microg/L and concentrations ranged from 100 to 1,000 microg/L. While AC was the most efficient adsorbent material, both alternative adsorbent materials showed good adsorption efficiencies for all ten xenobiotics (from 50 to 100 % depending on the xenobiotic/adsorbent material pair). For all the targeted xenobiotics, at lower concentrations, EC presented the best adsorption potential with higher partition coefficients, confirming the results in terms of removal efficiencies. Nevertheless, Zeolite presents virtually the same adsorption potential for both high and low xenobiotics concentrations to be treated. According to this first batch investigation, ZE and EC could be used as alternative absorbent materials to AC in WWTP.
(Environmental Science and Pollution Research. vol. 21, n° 0944-1344, pp. 5660-5668, 26/06/2026)
UR MALY, IRSTEA, EPOC, EPHE, PSL, UB, INSU - CNRS, CNRS, UMR Qualisud, Cirad, UM1, UM2, Montpellier SupAgro, AU, UR, UM, Montpellier SupAgro
Single and mixture effects of pesticides and a degradation product on fluvial biofilms
The Morcille River located in the Beaujolais vineyard area (Eastern France) is subjected to strong vine-growing pressure leading to the contamination by a range of herbicides and fungicides of the surrounding freshwater environment. Particularly high concentrations of norflurazon, desmethyl norflurazon and tebuconazole were recorded in spring 2010 at the downstream site of the river. Despite their occurrence in rivers, scarce toxicity data are available for these products, in particular in the case of desmethyl norflurazon (main norflurazon degradation product). Furthermore, the toxicity data are generally available only for single compounds and are issued from single species toxicity tests, leading to a lack of ecological relevance. Consequently, this study was undertaken to evaluate the toxic effects of norflurazon, desmethyl norflurazon and tebuconazole singly and in a ternary mixture on fluvial biofilm. Toxicity tests were performed in microplates for 48 h. Photosynthetic endpointsweremeasured using pulse amplitude-modulated fluorometry; diatom densities and taxonomic composition were determined. After 48 h of exposure, significant effects on optimal quantumyield (Fv/Fm) for desmethyl norflurazon and mixturewere observed.
(Environmental Monitoring and Assessment. vol. 186, n° 0167-6369, pp. 3931-3939, 26/06/2026)
UR EABX, IRSTEA, EPOC, EPHE, PSL, UB, INSU - CNRS, CNRS
A 1D stabilized finite element model for non-hydrostatic wave breaking and run-up
(. vol. 77, 26/06/2026)
BACCHUS, Inria, UB, CNRS, IMB, UB, Bordeaux INP, CNRS, EPOC, EPHE, PSL, UB, INSU - CNRS, CNRS
Video Monitoring and Field Measurements of a Rapidly Evolving Coastal System: the River Mouth and Sand Spit of the Mataquito River in Chile
The understanding of morphological processes controlling the evolution of sand spit reformation after a tsunami impact is a challenging and interesting topic, especially in highly energetic and micro tidal environments. A field campaign performed during December 2012 at the Mataquito River mouth in Chile, allowed us to simultaneously monitor topo-bathymetry evolution, wave climate, tidal range, swash zone dynamics and upper beach face evolution over a portion of its sand spit. A video system was set up for a continuous and long-term monitoring of the evolution of the river mouth and sand spit. Primarily, in this work we focus on the application of a video-derived shoreline detection method to assess shoreline evolution and beach cusps migration at hourly scales. We test the method performance on short-term episodic migration of beach cusps recorded during the campaign. Beach face variations at a daily scale were observed, which can be attributed to the migration of beach cusps in the alongshore direction, and linked to wave forcing and alongshore sediment transport.
(Journal of Coastal Research. vol. SI 70, n° 0749-0208, pp. 639-644, 26/06/2026)
EPOC, EPHE, PSL, UB, INSU - CNRS, CNRS, ECOLA, LEGOS, IRD, UT3, Comue de Toulouse, INSU - CNRS, CNES, CNRS
Beach cusp dynamics on a reflective beach
Beach cusps are common feature of steep reflective and intermediate beaches. However very few observations reported double coupled cusp systems. Here we present a data set of observations of a beach exhibiting two sets of beach cusps. Data were collected at Grand Popo Beach (Benin, West Africa) in February 2013. Daily topographic survey along a 380m long stretch of shore allowed observing the dynamic of the two set of beach cusps. At the beginning of the field survey, we clearly observe two sets of cusps : the upper beach cusps system is relatively asymetric with a typical wavelength of about 45 m while the lower beach cusps system is relatively symmetric with a typical wave length slightly shorter (about 35 m). After two days, we measured the total destruction of the lower set of beach cusps while the upper set of beach cusps was only partially des tructed. Data suggest that destruction of the lowerbeach cusp system may be related to persistent accretions conditions and/or calm conditions but probably also to the transition from wave- driven circulation dominated by weak alongshore currents with flash and swash rips, to a second period characterized by dominant longshore current further increasing in speed, and rare swash rips. On the other hand the disappearance of the western upper beach cusp might be related to an accretion pattern and to the merging of two individual features. Our observations, consistent with previous works, suggest that beach cusps certainly arise as a result of some combination of erosion and accretion.
(Journal of Coastal Research. vol. SI 70, n° 0749-0208, pp. 669-674, 26/06/2026)
EPOC, EPHE, PSL, UB, INSU - CNRS, CNRS, ECOLA, LEGOS, IRD, UT3, Comue de Toulouse, INSU - CNRS, CNES, CNRS, LEGOS, IRD, UT3, Comue de Toulouse, INSU - CNRS, CNES, CNRS, UAC
Morphodynamic characterisation of the human-impacted Bight of Benin sand barrier coast, West Africa
(Journal of Coastal Research. vol. SI 70, n° 0749-0208, pp. 079-083, 26/06/2026)
CEREGE, IRD, INRA, AMU, CdF (institution), INSU - CNRS, CNRS, ECOLA, LEGOS, IRD, UT3, Comue de Toulouse, INSU - CNRS, CNES, CNRS, EPOC, EPHE, PSL, UB, INSU - CNRS, CNRS, OLVAC, LEGOS, IRD, UT3, Comue de Toulouse, INSU - CNRS, CNES, CNRS
Fluid Seepage in Relation to Seabed Deformation on the Central Nile Deep-Sea Fan, Part 1: Evidence from Sidescan Sonar Data,
The central Nile Deep-Sea Fan contains a broad area of seabed destabilisation in association with fluid seepage: slope-parallel sediment undulations are associated with multibeam high-backscatter patches (HBPs) related to authigenic carbonates. During the 2011 APINIL campaign, a deep-towed sidescan and profiling system (SAR) was used to acquire high-resolution data along three transects across water depths of 1,700-2,650 m. Three seabed domains are distinguished, all developed within stratified sediments overlying mass-transport deposits (MTDs). Upslope of the undulations (<1,950 m), sidescan HBPs record focused fluid seepage via seabed cracks. In the western area of undulations, sidescan HBPs are distinct from intermediate-backscatter patches (IBPs) that extend up to 850 m parallel to the undulations, mainly along their downslope flanks; some contain sub-circular HBPs up to 300 m wide, three associated with smaller (<10 m) hydroacoustic gas flares. Focused fluid seeps are inferred to have shifted over time to form elongate carbonate pavements, preferentially along the footwalls of faults beneath the undulations that provide pathways for fluid flow. In contrast, in the eastern area of undulations, sidescan imagery reveal only slope-transverse furrows formed by turbulent flows, interpreted to indicate that fossil carbonates sampled during submersible operations have been exhumed by erosion.
(Advances in Natural and Technological Hazards Research. vol. 37, pp. 129-139, 26/06/2026)
GEOAZUR 7329, INSU - CNRS, UniCA, CNRS, IRD [Occitanie], IRD, UniCA, OGS, IFREMER, EPOC, EPHE, PSL, UB, INSU - CNRS, CNRS
Contributions and potential impacts of seven priority substances (As, Cd, Cu, Cr, Ni, Pb, and Zn) to a major European Estuary (Gironde Estuary, France) from urban wastewater
Urban wastewater metal inputs into coastal systems are of increasing interest to both scientists and managers facing restrictive environmental protection policies, population increase and changing metal applications. However, their impact and contribution to metal loads in estuarine and coastal environments is widely unknown due to the lack of (i) monitoring in both artificial and natural aquatic systems and (ii) an understanding of control parameters, such as spatial and temporal variations in hydrological conditions. We investigated the daily concentrations, fluxes and dynamics of seven EU priority contaminants (potentially toxic metals Cd, Cu, Cr, Ni, Pb, Zn and the metalloid As) transported by the Garonne River (La Réole site; watershed area ~ 57,000 km2) to those released into the freshwater reaches of the Gironde Estuary (Garonne Branch) by two main wastewater treatment plants (WWTPs) of Bordeaux under low river discharge and contrasting rainfall situations. During short intense summer rainstorms, wastewater flow into the WWTPs increased by up to 150% and 60%, respectively, resulting in an increase of 70% (As) to 200% (Pb) for fluxes entering the treatment plants. Overall resulting WWTP particulate and dissolved effluent concentrations were up to 2 (Cr), 3 (Pb, Cu and Ni) and 5 (Cd and Zn) times higher than measured upstream in the Garonne River, respectively. During low-discharge, maximum outlet fluxes at the WWTPs were similar to respective watershed-derived fluxes in the Garonne River. During rain events, Pb in all fractions, total and dissolved Cu and total and particulate Zn fluxes entering the fluvial estuary were close to the respective minimum flux values at the La Réole site. Furthermore, during rain episodes, particulate Cu and dissolved Zn fluxes from the WWTPs to the fluvial estuary were greater than those transported by the Garonne River at the La Réole site. Mixing of treated wastewater with highly turbid estuarine freshwater most likely results in a re-equilibration between the dissolved and particulate phases, although biogeochemical processes in downstream estuarine turbidity and salinity gradients may partly reverse contaminant adsorption on estuarine particles. Accordingly, urban wastewater contaminant release clearly impacts estuarine water quality before being expulsed to the Bay of Biscay.
(Marine Chemistry. vol. 167, n° 0304-4203, pp. 123-134, 26/06/2026)
EPOC, EPHE, PSL, UB, INSU - CNRS, CNRS
Technical, economic and environmental evaluation of advanced tertiary treatments for micropollutants removal (oxidation and adsorption)
Two pilots for tertiary treatment, an advanced oxidation processes (AOP - O3/UV/H2O2) pilot and a granular activated carbon pilot, were tested in three different wastewater treatment plants after a secondary treatment. A total of 64 micropollutants including drugs, pesticides, alkylphenols, PAHs and metals were analysed in the samples at the inlet and the outlet of the pilots. The tertiary treatments studied (ozone, AOP and activated carbon) were efficient for the removal of most of the compounds analysed in this study, except metals. The addition of hydrogen peroxide to ozone increased the number of substances well removed but it did not improve the removal of substances that readily react with ozone (such as betablockers or carbamazepine). The other AOP (ozone/H2O2 and UV/H2O2) did not improve the number of substances well removed in comparison with ozone alone. The granular activated carbon was still efficient (R>70%) after 6 months working 24/7 for most of the drugs and the urea and triazine pesticides. The 5 technologies studied were sized at full scale in order to calculate their cost for two sizes of WWTP. The implementation of a tertiary treatment on a 60 000 to 200 000 PE WWTP would increase the wastewater treatment cost by 1,5 to 17,6 euros cents per cubic meter treated according to the technology and the removal objective. Concerning the environmental impact, for the big WWTP, the activated carbon is more impacting than the other processes for most of the impacts calculated. The order of POA by increasing environmental impact is ozone < ozone/H2O2 < ozone/UV ~ UV/H2O2. For the medium size WWTP however, the activated carbon is comparable to the other solutions regarding environmental impact.
(pp. 4 p., 26/06/2026)
CIRSEE, EPOC, EPHE, PSL, UB, INSU - CNRS, CNRS, UR MALY, IRSTEA
Developmental toxicity of PAH mixtures in fish early life stages. Part I: adverse effects in rainbow trout
A new gravel-contact assay using rainbow trout, Oncorhynchus mykiss, embryos was developed to assess the toxicity of polycyclic aromatic hydrocarbons (PAHs) and other hydrophobic compounds. Environmentally realistic exposure conditions were mimicked with a direct exposure of eyed rainbow trout embryos incubated onto chemical-spiked gravels until hatching at 10 °C. Several endpoints were recorded including survival, hatching delay, hatching success, biometry, developmental abnormalities, and DNA damage (comet and micronucleus assays). This bioassay was firstly tested with two model PAHs, fluoranthene and benzo[a]pyrene. Then, the method was applied to compare the toxicity of three PAH complex mixtures characterized by different PAH compositions: a pyrolytic extract from a PAH-contaminated sediment (Seine estuary, France) and two petrogenic extracts from Arabian Light and Erika oils, at two environmental concentrations, 3 and 10 μg g−1 sum of PAHs. The degree and spectrum of toxicity were different according to the extract considered. Acute effects including embryo mortality and decreased hatching success were observed only for Erika oil extract. Arabian Light and pyrolytic extracts induced mainly sublethal effects including reduced larvae size and hemorrhages. Arabian Light and Erika extracts both induced repairable DNA damage as revealed by the comet assay versus the micronucleus assay. The concentration and proportion of methylphenanthrenes and methylanthracenes appeared to drive the toxicity of the three PAH fractions tested, featuring a toxic gradient as follows: pyrolytic < Arabian Light < Erika. The minimal concentration causing developmental defects was as low as 0.7 μg g−1 sum of PAHs, indicating the high sensitivity of the assay and validating its use for toxicity assessment of particle-bound pollutants.
(Environmental Science and Pollution Research. vol. 21, n° 0944-1344, pp. 13720-13731, 26/06/2026)
UB, EPOC, EPHE, PSL, UB, INSU - CNRS, CNRS, LPGP, INRA, Biosit : Biologie - Santé - Innovation Technologique, BE, IFREMER